室温下合成了6种未见报道的固态含能配合物M(BTA)(bpy)m.nH2O(M=Mn,m=1,n=1;M=Co,m=2,n=5;M=Ni,m=2,n=6;M=Cu,m=2,n=0;M=Zn,m=2,n=1;M=Pb,m=1,n=0;BTA=N,N’-二四唑胺离子,bpy=2,2’-联吡啶),对它们进行了组成、红外光谱、密度等表征。测定了298.15 K下各配合物的液相生成反应焓变△rHmθ,改变液相反应温度,在实验和计算基础上,得到了液相生成反应的热力学参数(活化焓△Hθ≠、活化熵△S≠θ和活化自由能△Gθ≠)、速率常数k和动力学参数(表现活化能E、频率因子ln[A/s]和反应级数n)。 Six kinds of unreported solid - state complexes M (BTA) (bpy) m.nH2O were synthesized at room temperature (M = Mn, m = 1, n = 1; M = Zn, m = 2, n = 6; M = Cu, m = 2, n = 0; N, N’-ditetrazolium ion, bpy = 2,2’-bipyridyl) were synthesized and their compositions, IR spectra and density were characterized. The enthalpy change △ rHmθ of the liquid phase formation reaction was measured at 298.15 K. The liquid phase reaction temperature was changed. Based on the experiment and calculation, the thermodynamic parameters (activation enthalpy △ Hθ ≠, activation entropy △ S ≠ θ and activation free energy ΔGθ ≠), rate constant k and kinetic parameters (expression of activation energy E, frequency factor ln [A / s] and reaction order n).