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旋光性四面体型过渡金属配合物的圆二色光谱(CD)在d-d跃迁区的特征谱线反映了该类配合物的构型特征。从极化度的多级圆球不对称性模型出发,可将这类配合物的构型与CD在d-d跃迁区的特征谱线之间建立起直接的联系。
The characteristic line of the circular dichroism (CD) of the optically active tetrahedral transition metal complex in the d-d transition region reflects the configurational characteristics of the complexes. Starting from the multipolar asymmetry model of polarization, we can establish a direct relationship between the configuration of these complexes and the characteristic curve of CD in the d-d transition region.