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以联苯二胺及二甲基联苯二胺为原料,合成了相应的N,N′-二氯联苯醌胺单体,并以二价镍配合物为催化剂与二连噻吩共聚得到了相应的交替共聚物。所得聚合物通过FT-IR,1H-NMR进行了表征。所得聚合物紫外-可见光谱分别在330、437、327、410nm处最大吸收峰出现。所得聚合物在-0.1～0.8V之间进行循环伏安分析,每一个聚合物都观察到两对氧化峰和还原峰分别在(Epa=0.40V/Epc=0.31V和Epa=0.70V/Epc=0.56V)和(Epa=0.33V/Epc=0.28V和Epa=0.63V/Epc=0.50V)。
The corresponding N, N’-dichlorobiphenylamine amine monomers were synthesized from biphenylenediamine and dimethylbiphenylenediamine. Copolymerization with dihydrothiophene with divalent nickel complexes as catalyst The corresponding alternating copolymer. The obtained polymer was characterized by FT-IR and 1H-NMR. The resulting polymer UV - visible spectrum at 330,437,327,410 nm, respectively, the maximum absorption peak appears. The obtained polymer was subjected to cyclic voltammetry between -0.1 and 0.8 V and two pairs of oxidation and reduction peaks were observed for each polymer at (Epa = 0.40 V / Epc = 0.31 V and Epa = 0.70 V / Epc = 0.56V) and (Epa = 0.33V / Epc = 0.28V and Epa = 0.63V / Epc = 0.50V).