手性磷-烯配体在不对称催化反应中的应用近年来受到化学家们的关注,已经成为一个热门的研究领域.磷-烯配体作为一类新兴杂化烯烃配体,将具有强配位能力的磷原子与配位方式特殊但配位能力相对较弱的碳-碳双键结合在一起,兼具了部分手性膦配体和手性双烯配体的优点,在一些过渡金属如铑、钯、铱等催化的不对称反应中表现出独特的催化性能,不但能高效催化反应,而且能取得优异的对映选择性.本文综述了自2004年首例磷-烯配体的合成及应用报道以来该领域的研究进展,对过去十几年中发展的各种手性磷-烯配体的结构特征、合成方法以及它们在不同催化不对称反应中的应用进行了分类概括,期望为未来进一步拓展手性烯烃配体的类型和应用提供思考和方向. The application of chiral phosphorus-olefin ligands in asymmetric catalytic reactions has attracted much attention of chemists in recent years and has become a hot research field.As a new class of heteroleptic olefin ligands, phosphorus-olefin ligands will have strong Coordination ability of the phosphorus atom with a special coordination but the coordination ability is relatively weak carbon-carbon double bond together, both the advantages of some chiral phosphine ligand and chiral diene ligand, in some transition Metals such as rhodium, palladium, iridium and other catalytic asymmetric reactions showed unique catalytic properties, not only can efficiently catalyze the reaction, and can achieve excellent enantioselectivity.This paper reviews the first phosphorus-ene ligand The synthesis and application reports of the research progress in this field since the past ten years on the development of a variety of chiral phosphorus - ene ligands structural characteristics, synthesis methods and their application in different catalytic asymmetric reactions are summarized It is hoped that this will provide us with ideas and direction for further expanding the types and applications of chiral olefin ligands in the future.