通过半连续乳液聚合的方法获得了单分散性好，数均粒径为７０６９ｎｍ的苯乙烯，丙烯酸丁酯和丙烯酸（Ｓｔ／ＢＡ／ＡＡ）高分子微球，并通过毛细压力法，成功地在玻璃基体上组装成了紧密的二维有序排列点阵结构．点阵结构的形成过程可分为成核和增长两个阶段．在二维有序排列形成过程中，微粒之间的相互排斥作用可通过添加一定浓度的电解质来进行调节．组装后的二维有序排列用扫描电镜进行了观察． By means of semi-continuous emulsion polymerization, styrene, butyl acrylate and acrylic acid (St / BA / AA) polymer microspheres with good monodispersity and average number average particle size of 7069 nm were obtained. By capillary pressure method, In the glass matrix assembled into a close two-dimensional ordered lattice structure. Lattice structure formation process can be divided into two stages of nucleation and growth. In the formation of two-dimensional ordered arrangement, the mutual repulsion between the particles can be adjusted by adding a certain concentration of electrolyte. After the assembly of two-dimensional ordered by scanning electron microscopy was observed.