论文部分内容阅读
许多反应可用于合成含金属—金属键的化合物。含钼—锗键,钨—锗键的双金属化合物的一种有效的合成方法是利用二氯锗烯二氧六环络合物(dichlorogermylene dioxane complex)为原料,通过对金属—卤素键的插入反应合成金属—金属键。例如:
Many reactions can be used to synthesize metal-metal bond containing compounds. An effective synthesis method of the bimetallic compound containing molybdenum-germanium bond and tungsten-germanium bond is to use a dichlorogermylene dioxane complex as a starting material and insert the metal-halogen bond The reaction synthesizes metal-metal bonds. E.g: