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在水和甲醇的混合溶剂中，邻菲绕啉和 ＣｕＣｌ２·２Ｈ２Ｏ在己二酸和碳酸钠存在下反应给 出［Ｃｕ（ｐｈｅｎ）２Ｃｌ］ＯＨ·５．５Ｈ２Ｏ．单晶Ｘ－射线衍射分析表明，晶体属单斜晶系， Ｃ２／ｃ（Ｎｏ．１５） 空间群，晶胞参数：α＝ ２．３３２２（４）ｎｍ， ｂ＝３．０２８６（６）ｎｍ， ｃ＝０．７５０３（１）ｎｍ， β＝ ９７．８０（１）°，Ｖ＝ ５．２５１（２） ｎｍ３， Ｄｃ＝ １．４５６ ｇ／ｃｍ３，Ｚ＝ ８，Ｆ（０００）＝ ２ ３８４， ５ ７９１个独立 衍射点中，２５８０个可观测点满足Ｆ２０≥２σ（Ｆ２ｏ），Ｒ＝０．０９１，ｗＲ２＝０．１３７３．标题配合物的 晶体结构由［ Ｃｕ（ｐｈｅｎ）２ Ｃｌ］＋配阳离子， ＯＨ－离子和结晶水分子组成． Ｃｕ原子与１个Ｃｌ原子 和分属于２个邻菲绕啉配体的４个Ｎ原子配位形成畸变三角双锥，其中两个Ｎ原子位于轴 向位置，轴向 Ｃｕ－Ｎ的键长为 ０．１９６９（６）和 ０．１９８１（５）ｎｍ，径向 Ｃｕ－Ｎ的键长为 ０．２０８ ７（５）和 ０．２１０ ５（５）ｎｍ， Ｃｕ－ Ｃｌ的键长为 ０．２３３ ５（２）ｎｍ．通过芳环堆积作用，配阳离 子组装形成二维层结构，ＯＨ－离子和水分子位于层之间．
In a mixed solvent of water and methanol, phenanthroline and CuCl2.2H2O are reacted in the presence of adipic acid and sodium carbonate to give [Cu (phen) 2Cl] OH.5.5H2O. Single crystal X-ray diffraction analysis showed that the crystal belongs to the monoclinic space group C2 / c (No.15) with unit cell parameters α = 2.3322 (4) nm and b = 3.0286 (6) nm , C = 0.7503 (1) nm, β = 97.80 (1) °, V = 5.251 (2) nm3, Dc = 1.456 g / cm3, Z = 8, F Among 384 and 5 791 independent diffraction points, 2580 observable points satisfy F20≥2σ (F2o), R = 0.091, and wR2 = 0.1373. The crystal structure of the title complex consists of [Cu (phen) 2 Cl] + cations, OH- ions and crystal water molecules. Cu atom collides with one Cl atom and four N atoms belonging to two phenanthroline ligands to form a distorted triangular double cone in which two N atoms are located at axial positions and the bond length of the axial Cu-N is 0.1969 (6) and 0.1981 (5) nm, the bond lengths of Cu-N in the radial direction are 0.208 7 (5) and 0.210 5 (5) nm, respectively. 233 5 (2) nm. Through the aromatic ring stacking effect, with the formation of two-dimensional cation-layer structure, OH- ions and water molecules located between the layers.