In Situ Investigation of Si-Poisoning Effect in Al-Cu-Si Alloys Inoculated by Al-5Ti-1B

来源 :金属学报(英文版) | 被引量 : 0次 | 上传用户:yangyang03
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In situ synchrotron X-radiography was carried out on Al-13Cu and Al-13Cu-7Si alloys with and without addition of Al-5Ti-1B master alloy.The effects of Si content on grain growth and the solute-suppressed nucleation zone (SSNZ) were quantitatively studied.The average grain size can be refined to 164 μm of Al-13Cu alloy inoculated by Al-5Ti-1B.After addition of 7% Si content,a large number of TiB2 sites in the melt lost the inoculating ability due to “Si poisoning.” The radius of the dendrite tip curvature of Al-13Cu is more than two times as large as that of Al-13Cu-7Si.The sharper tip is able to disperse the solute more effectively and thus grains can grow more rapidly.This causes that the dendrite arm growth rate with addition of 7% Si solute is about 2.6 times that of no Si addition.In addition,the solute enrichment in the SSNZ of Al-13Cu is faster,and the area change of SSNZ is slower than that of Al-13Cu-7Si.Thus more nucleation sites in the SSNZ cannot be activated with addition of Si.This study will shed light on the understanding of Si poisoning in casting Al-Cu-Si alloys.
其他文献
The detrimental effects of carbides and porosity on the fatigue crack initiation and propagation of nickel-based single-crystal superalloys have been reported by many previous studies.However,few studies have quantitatively compared the fatigue damaging e
以Ni-11Cr合金作为基材,采用多弧离子镀工艺在其表面制备Cr/AlCrN与Cr/AlCrSiN涂层,并对其在700~900℃温度下进行真空热处理,研究热处理温度及Si元素对Cr/AlCr(Si)N涂层组织和红外反射率的影响.结果表明:真空热处理后两涂层形成了Cr2 O3与Al2 CrO3的特征峰,900℃热处理后,氧化物晶体结构特征衍射峰明显增加.两种涂层的组织呈柱状形态,在Cr/AlCrN涂层中存在许多hcp-CrN纳米晶;Cr/AlCrSiN涂层中形成了粒径尺寸均匀的hcp-AlN纳米晶.真空热处
Distributions of electromagnetic fields and induced forced flow inside a metal melt are crucial to understand the grain refine-ment of the metal driven by pulsed magneto-oscillation (PMO).In the present study,PMO-induced electromagnetic fields and forced
The effects of Cl-,Cu2+ and Fe3+ ions and their combinations on the corrosion behaviour of aluminium alloy 6063 (AA6063)in ethylene glycol and water solutions at 50 ℃ were investigated by electrochemical and immersion methods.Cl-resulted in pitting corros
Characterizing the microstructure and deformation mechanism associated with the performances and properties of metallic materials is of great importance in understanding the microstructure-property relationship.The past few decades have wit-nessed the rap
Synchrotron radiation was observed for the first time by Haber et al.at General Electric in the United States in 1947 in a 70-MeV electron synchrotron.The development of synchrotron radiation light source has gone through four generations since the 1960s.
期刊
Metastable phases formed during vitrification or devitrification open an avenue to study the intrinsic structural hierarchy in amorphous materials.The phase transformation sequence of Al89Ce 11 amorphous ribbon was investigated using differen-tial scannin
Transition metal oxides gain considerable research attentions as potential anode materials for lithium ion batteries,but their applications are hindered due to their poor electronic conductivity,weak cycle stability and drastic volume change.Here,a NiO@gr
The evolution of the 3D Fe-rich phases of Al-7.0Si-1.2Fe alloys with different Mn contents was visualized and character-ized using synchrotron X-ray computed tomography,and the effect of Fe-rich phases with typical morphologies on the fracture behavior du