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In situ synchrotron X-radiography was carried out on Al-13Cu and Al-13Cu-7Si alloys with and without addition of Al-5Ti-1B master alloy.The effects of Si content on grain growth and the solute-suppressed nucleation zone (SSNZ) were quantitatively studied.The average grain size can be refined to 164 μm of Al-13Cu alloy inoculated by Al-5Ti-1B.After addition of 7% Si content,a large number of TiB2 sites in the melt lost the inoculating ability due to “Si poisoning.” The radius of the dendrite tip curvature of Al-13Cu is more than two times as large as that of Al-13Cu-7Si.The sharper tip is able to disperse the solute more effectively and thus grains can grow more rapidly.This causes that the dendrite arm growth rate with addition of 7% Si solute is about 2.6 times that of no Si addition.In addition,the solute enrichment in the SSNZ of Al-13Cu is faster,and the area change of SSNZ is slower than that of Al-13Cu-7Si.Thus more nucleation sites in the SSNZ cannot be activated with addition of Si.This study will shed light on the understanding of Si poisoning in casting Al-Cu-Si alloys.