Enhancement of upconversion luminescence of YAlO_3:Er~(3+) by Gd~(3+) doping

来源 :Chinese Optics Letters | 被引量 : 0次 | 上传用户:MUNICH2009
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The upconversion luminescences of YAlO3:Er3+ phosphor co-doping with different Gd3+ concentrations are investigated under the excitation of 980- and 532-nm diode lasers. A near ultraviolet upconversion emission at 410 nm is observed in YAlO3 under 532-nm excitation. Moreover, the inactive Gd3+ ions can improve the upconversion intensity efficiently in a certain range of concentration. Under 980-nm excitation, the visible upconversion emissions at 546 and 646 nm are enhanced by about 10 and 8 times at the Gd3+ concentration of 40%, respectively. The upconversion emission at 410 nm under 532-nm excitation is also enhanced by 7 times. The substitution of Gd3+ ions for Y3+ sites changes the local symmetry of Er3+, leading to the improvement of upconversion efficiency. The upconversion luminescence of YAlO3: Er3 + phosphor co-doping with different Gd3 + concentrations are investigated under the excitation of 980- and 532-nm diode lasers. A near ultraviolet upconversion emission at 410 nm is observed in YAlO3 under 532- the inactive Gd3 + ions can improve the upconversion intensity efficiently in a certain range of concentrations. Under 980-nm excitation, the visible upconversion emissions at 546 and 646 nm are enhanced by about 10 and 8 times at the Gd3 + concentration of 40%, respectively. The upconversion emission at 410 nm under 532-nm excitation is also enhanced by 7 times. The substitution of Gd3 + ions for Y3 + sites changes the local symmetry of Er3 +, leading to the improvement of upconversion efficiency.
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