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A chain-like coordination polymer with the chemical formula of {[Ni2Mn2L2(CH3CH2OH)-(H2O)]·CH3OH·2H2O}n has been synthesized by the assembly reaction of K2NiL·H2O and Mn(OAC)2·4H2O with a 1:1 mole ratio in methanol,where OAC-=CH3COO-and H4L=2-hydroxy-3-[(E)-({2-[(2-hydroxybenzoyl)imino]ethyl}imino)methyl]benzoic acid.The crystal structure was determined by single-crystal X-ray diffraction analysis.It belongs to the triclinic system,space group P1,with a=9.9464(8),b=13.4718(11),c=14.3877(12),α=87.1930(10),β=85.4280(10),γ=74.6470(10)°,V=1852.4(3)3,Z=2,Dc=1.807g/cm3,Mr=1008.03,λ(MoKα)=0.71073,μ(MoKα)=1.794 mm-1,F(000)=1032,R=0.0527 and wR=0.1284(Ⅰ>2σ(Ⅰ)).The compound exhibits a chain-like structure formed by dissymmetrical tetranuclear units.
A chain-like coordination polymer with the chemical formula of {[Ni2Mn2L2 (CH3CH2OH) - (H2O)] · CH3OH · 2H2O} n has been synthesized by the assembly reaction of K2NiL · H2O and Mn (OAC) 2 · 4H2O with a 1 : 1 mole ratio in methanol, where OAC- = CH3COO-and H4L = 2-hydroxy-3 - [(2-hydroxybenzoyl) imino] ethyl} structure was determined by single-crystal X-ray diffraction analysis. lt belongs to the triclinic system, space group P1 with a = 9.9464 (8), b = 13.4718 (11), c = 14.3877 (10) β = 85.4280 (10) γ = 74.6470 (10) ° V = 1852.4 (3) 3 Z = 2 Dc = 1.807g / cm3 Mr = 1008.03 λ (MoKα) = 0.71073 , μ (MoKα) = 1.794 mm-1, F (000) = 1032, R = 0.0527 and wR = 0.1284 (I> 2σ (Ⅰ)). The compound exhibits a chain-like structure formed by dissymmetrical tetranuclear units.