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  5. Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex: [K(DB18C6)]2[Pd(SCN)4]

Cation-π Interactions. Synthesis and Crystal Structure of Palladium Complex: [K(DB18C6)]2[Pd(SCN)4]

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：rwteng
【摘 要】
：
A novel Pd(II)-dibenzo-18-crown-6 (DB18C6) complex [K(DB18C6)]2[Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state,
【作 者】
：
Jian Min DOU Ying LIU Lan Ying 
【机 构】
：
Department of Chemistry and Biology,Research Center of Analysis and Measurement,Key Laboratory of Ap
【出 处】
：
中国化学快报（英文版）
【发表日期】
：
2004年期
【关键词】
：
Cation-p interactions crown ether crystal structure palladium complex 
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论文部分内容阅读
A novel Pd(II)-dibenzo-18-crown-6 (DB18C6) complex [K(DB18C6)]2[Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi-one-dimensional infinite chain of two [K(DB18C6)] + complex cations and a [Pd(SCN)4]2- anion bridged by K+-p interactions between adjacent [K(DB18C6)] + units.
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