本文论述了共面堆积的一维线性聚合酞菁的合成方法、结构表征及电学性质。聚合酞菁按中心原子的化合价可分成三类 ,其中第一类的研究报道较多。聚合物的电导率主要受 3个因素的影响 :中心原子 ,桥连配体 ,外围取代基。其中对电导率影响最大的是桥连配体 ,由氰根、硫氰酸根、吡嗪、四嗪等含有π电子的化合物作为配体形成的聚合物在未掺杂时即具有较高的电导率。 This paper deals with the synthesis, characterization and electrical properties of one-dimensional linear polymeric phthalocyanines that are coplanarly stacked. Polymerization of phthalocyanine by the valence of the central atom can be divided into three categories, of which the first type of research reported more. The conductivity of polymers is mainly affected by three factors: the central atom, bridged ligands, peripheral substituents. One of the most influential on the conductivity of the bridged ligands, from cyanide, thiocyanate, pyrazine, tetrazines and other compounds containing π-electron as a ligand to form a polymer without doping when it has a high conductivity rate.