Performance of Sn-Cu Alloy Anode at Low Temperature

来源 :材料科学技术学报(英文版) | 被引量 : 0次 | 上传用户:yoki1120
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Sn-Cu alloy anode was prepared by pulsed electrodeposition for lithium ion batteries, and its electrochemical performance was tested at Iow temperature. When temperature decreased from 25℃ to -20℃, the Sn-Cu alloy anode provided the capacity retentions of 76% in the electrolyte of 1 mol/L LiBF4/EC+EMC+γBL and 51% in the electrolyte of 1 mol/L LiPF6/EC+DMC+DEC. Under the same conditions, the graphite anode presented the capacity retentions of only 41% and 18%, respectively. The Sn-Cu alloy anode showed better performance in the electrolyte of 1 mol/L LiBF4/EC+EMC+γBL than in the electrolyte of 1 mol/L LiPF6/EC+DMC+DEC, and kept much higher capacity retention than that of graphite at -20℃. The Sn-Cu alloy anode in the electrolyte of 1 mol/L LiBF4/EC+EMC+γBL (1:1:1, volume ratio) is promising for Iow temperature application of lithium batteries.
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