【摘 要】
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A new electrochemical strategy for trifluoromethylation/cyclization using TfNHNHBoc as a CF3 source was established.This approach was realized by the direct electrolysis of TfNHNHBoc under external oxidant-free and catalyst-free conditions,and afforded va
【机 构】
：
Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power,Shanghai Un
论文部分内容阅读
A new electrochemical strategy for trifluoromethylation/cyclization using TfNHNHBoc as a CF3 source was established.This approach was realized by the direct electrolysis of TfNHNHBoc under external oxidant-free and catalyst-free conditions,and afforded various trifluoromethylated oxindoles with good functional group compatibility and broad substrate scope.Preliminary mechanistic studies show that the reaction proceeds by a radical process.
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