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在常温常压下,利用脉冲电晕等离子体研究了甲烷和二氧化碳的转化。在等离子体一催化反应装置上,测试了Pd/γ-Al2O3对甲烷偶联的催化活性。实验发现,在脉冲电晕等离子体作用下,甲烷和二氧化碳被转化为C2烃、CO、H2、O2、少量积碳和高碳烃;在等离子体条件下引入Pd/γ-Al2O3催化剂,能够有效地改善甲烷偶联产物C2烃的分布,有利于生成更高附加值的乙烯。
Methane and carbon dioxide conversion was studied using pulsed corona plasma at ambient temperature and pressure. Catalytic activity of Pd / γ-Al2O3 for methane coupling was tested on a plasma-catalyzed reaction apparatus. It was found that under the action of pulsed corona plasma, methane and carbon dioxide were converted to C2 hydrocarbons, CO, H2, O2, a small amount of carbon deposition and high carbon hydrocarbons. The introduction of Pd / γ-Al2O3 catalyst under plasma conditions was effective Improve the methane coupling product C2 hydrocarbon distribution, help to generate higher value-added ethylene.