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A new carboxylate-phosphonate, [Zn3(O3PCH(CH3)COO)2(H2O)] 1, has been success- fully synthesized by hydrothermal technique and characterized by X-ray single-crystal structure analysis, elemental analysis and infrared spectroscopy. It crystallizes in monoclinic, space group P21/c with a = 4.9521(5), b = 21.953(3), c = 13.2266(18) ’, β = 100.704(2)o, V = 1412.9(3) ’3, Z = 4, Mr = 516.19, Dc = 2.427 g/cm3, F(000) = 1016, μ(MoKα) = 5.332 mm-1 and T = 293(2) K. The final R = 0.0605 and wR = 0.1354 for 2957 observed reflections with I > 2σ(I). The thermogravimetric analysis (TGA) and fluorescent measurement have been done. The structure of compound 1 is a 3D open framework with 32-atom channels.
A new carboxylate-phosphonate, [Zn3 (O3PCH (CH3) COO) 2 (H2O)] 1, has been success- fully synthesized by hydrothermal technique and characterized by X-ray single- crystal structure analysis, elemental analysis and infrared spectroscopy. It crystallizes in monoclinic space group P21 / c with a = 4.9521 (5), b = 21.953 (3), c = 13.2266 (18) ’, β = 100.704 = 4, Mr = 516.19, Dc = 2.427 g / cm3, F (000) = 1016, μ MoKα = 5.332 mm-1 and T = 293 2 K. The final R = 0.0605 and wR = 0.1354 for 2957 observed reflections with I> 2σ (I). The thermogravimetric analysis (TGA) and fluorescent measurement have been done. The structure of compound 1 is a 3D open framework with 32-atom channels.