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运用电化学暂态方法和现场时间分辨FTIR反射光谱研究甲酸在Pt(100)单晶电极上的解离吸附和氧化过程.深入认识了甲酸解离吸附的反应速率在-0.25至0.25V电位区间呈火山形变化的规律.根据电化学现场时间分辨红外光谱的研究结果,提出在研究反应动力学时避免甲酸解离吸附干扰的方法,为进一步研究甲酸在Pt(100)电极表面经活性中间体直接氧化至CO2的反应动力学奠定了基础.
Study on the Dissociative Adsorption and Oxidation of Formic Acid on Pt (100) Single Crystal Electrode by Electrochemical Transient Method and Field Time Resolved FTIR Spectroscopy. In-depth understanding of the reaction rate of formic acid dissociative adsorption potential range of -0.25 to 0.25V volcano-shaped changes in the law. According to the results of electrochemical in situ time-resolved infrared spectroscopy, a method to avoid the dissociation of formic acid in the study of reaction kinetics is proposed. In order to further study the kinetics of the direct oxidation of formic acid on Pt (100) electrode via active intermediate to CO2 Foundation.