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依据机械合金化引起固态反应非晶化(SSAR)机制,选择等原子成分合金的形成△Hf和自扩散激活能差△Hs为参数坐标构成的坐标系,揭示了机械合金化引起二元过渡族金属合金非晶化的规律,基于已有的实验事实,确定二元过渡族金属合金在机械合会化时形成非晶的条件为△Hf<-0.005750(△Hs)2+1.345636(△Hs)-58.744095.用核判据对已有实验结果的58个过渡族全属二元合金系统的研究表明,对其能否形成非晶的区分准确率高达96%.
According to the mechanism of solid reaction induced amorphization (SSAR) caused by mechanical alloying, the formation of coordinate system of parameter △ Hf and the difference of activation energy difference △ Hs of the atomic composition alloy is the parameter coordinate, which reveals that mechanical alloying causes binary transition group Based on the existing experimental facts, the conditions for the amorphous transition of binary binary transition metal alloys were found to be ΔHf <-0.005750 (ΔHs) 2 + 1.345636 (ΔHf) Hs) -58.744095. The study of 58 all transitional family binary systems with the experimental results using the nuclear criterion shows that the accuracy of distinguishing whether they are amorphous or not is as high as 96%.