论文部分内容阅读
运用电化学循环伏安(CV)和原位FTIR反射光谱方法,研究了丙三醇在Pt电极上的氧化过程。结果指出,丙三醇的氧化是一个复杂的表面过程,其间包括脱水、吸附、解离等步骤.根据CV和红外实验数据,本文提出了Pt电极上丙三醇解离吸附的表面反应机理和不同电位下丙三醇氧化的分子过程。
The oxidation of glycerol on Pt electrode was investigated by electrochemical cyclic voltammetry (CV) and in situ FTIR spectroscopy. The results indicate that the oxidation of glycerol is a complicated surface process, including the steps of dehydration, adsorption and dissociation.According to CV and infrared experimental data, this paper presents the surface reaction mechanism of glycerol dissociative adsorption on Pt electrode and Molecular processes of glycerol oxidation at different potentials.