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报导了两个Schiff碱配体的单核Mn（Ⅲ）配合物（[Mn（Ⅲ）（L1）（H2O）］4CIO。·ZH。O（1）和［Mn（ffi）（LZ）厂Ic。·ZH。O（2》的合成、晶体结构及性反X一衍射晶体结构分析证实：配合物1的晶体属于正交晶系，Pna21空间群．其晶胞参数为α＝10．932（7）A，b＝22．393（5）A，c＝8．960（3）A，V=2193（1）A3，Z＝4．2的晶体属于正交晶系，P212121空间群，α＝17．345（3）A，b＝17．905（2）A，c=7．789（1）A，V＝2418．9（6）A3，Z=4．电化学研究结果显示：配合2是稳定的电化学产物，而1在电场作用下容易歧化．由此说明配位环境是影响化合物稳定性的重要因素．
Reported the mononuclear Mn (III) complexes of two Schiff base ligands [Mn (III) (Ll) (H2O)] 4CIO.Z.O. and Mn (ffi) (LZ) The crystal structure of the complex 1 and the crystal structure of the anti-X-ray diffraction confirmed that the crystal of the complex 1 belongs to the orthorhombic Pna21 space group with the unit cell parameters of α = 10.932 ( 7) A, b = 22.393 (5) A, c = 8.960 (3) A, V = 2193 (1) A3 and Z = 4.2 belong to orthorhombic system, P212121 space group, α = 17.345 (3) A, b = 17.905 (2) A, c = 7.789 (1) A, V = 2418.9 (6) A3, Z = 4. Electrochemical studies showed that: 2 is a stable electrochemical product, and 1 is easily disproportionated under the action of an electric field, thus indicating that coordination environment is an important factor affecting the stability of the compound.