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以1,3-环己二酮、对溴苯甲醛和对甲基苯胺为原料,在水溶剂中,通过微波辅助一步合成标题化合物,实现了该类化合物的绿色合成.经单晶X射线分析,该化合物晶体属于斜方晶系,空间群Pbca,晶胞参数a=1.969 0(3)nm,b=2.132 6(3)nm,c=2.301 3(2)nm,α=90°,β=90°,γ=90°,相对分子质量Mr=461.36,V=9.66 3(2)nm3,晶胞密度Dc=1.268 g/cm3,Z=16,吸收系数μ(MoK)α=1.722 mm-1,F(000)=3 792.晶体结构用直接法解得,使用全矩阵最小二乘法对原子参数进行修正,最终偏离因子R=0.048 9,ωR=0.096 0.
The title compounds were synthesized by the one-step synthesis of 1,3-cyclohexanedione, p-bromobenzaldehyde and p-methylaniline in water solvent by microwave irradiation, and the green synthesis of these compounds was achieved.A single crystal X-ray analysis , The crystal belongs to the orthorhombic system with space group Pbca. The lattice parameters a = 1.969 0 (3) nm, b = 2.132 6 (3) nm, c = 2.301 3 = 90 °, γ = 90 °, relative molecular mass Mr = 461.36, V = 9.66 3 (2) nm3, cell density Dc = 1.268 g / cm3, 1, F (000) = 3 792. The crystal structure is solved by the direct method, using the full matrix least squares method to modify the atomic parameters, the final deviation factor R = 0.048 9, ωR = 0.096 0.