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A new Co 2(HPO 4) 2·H 2O has been hydrothermally synthesized firstly. Single crystal X-ray analysis indicates that this compound crystallizes in a hexagonal system, space group P6 5 with a=1.048 31(15) nm, b=1.048 31(15) nm, c=1.496 3(3) nm, α=90°, β=90°, γ=120°, V= 1.424 1(4) nm 3, μ=3.849 mm -1, Z=6, F(000)=960, D c=2.294 g/cm 3, R=0.072 1, wR= 0.212 1, S=1.182, Δρ max=1.671×10 3 e·nm -3 and (Δρ) min=-1.210×10 3 e·nm -3. Co 2(HPO 4) 2·H 2O is characterized by 1D 12-ring helical channels. Tetrahedral primary structure-building units of CoO 4 and PO 4 indicates the title compound has a zeotype framework.
A new Co 2 (HPO 4) 2 · H 2O has been hydrothermally synthesized first. Single crystal X-ray analysis indicates that this compound crystallizes in a hexagonal system, space group P 6 5 with a = 1.048 31 (15) nm, b = 1.048 31 15 nm c = 1.496 3 3 nm α = 90 ° β = 90 ° γ = 120 ° V = 1.424 1 4 nm 3 μ = 3.849 mm -1 Z = D = 2.294 g / cm 3, R = 0.072 1, wR = 0.212 1, S = 1.182, Δρ max = 1.671 × 10 3 e · nm -3 and (Δρ) min = -1.210 × 10 3 e · nm -3. Tetrahedral primary structure-building units of CoO 4 and PO 4 indicate the title compound has a zeotype framework.