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毛细管色谱分析中的区分效应(国内也译作“歧视”指由于样品各组分的挥发性、极性或浓度上的差别而造成定量的精密度与准确度的降低。分流进样中很易引起区分效应,许多研究者提出了克服这种效应的方法。Jennings曾建议用校正因子进行补偿;Bayer提出停流-分流进样方式;Hartigan则引入了一种高线性的全
Differentiation in Capillary Chromatography (Discrimination in China is also referred to as “Discrimination” due to differences in the volatility, polarity, or concentration of each component of a sample resulting in reduced precision and accuracy.) Split-flow injections can easily cause Distinguishing effects, many researchers have proposed ways to overcome this effect. Jennings suggested compensating with a correction factor; Bayer proposed stop-flow-split injection; and Hartigan introduced a high-linearity