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钛、锆金属有机化合物的水相化学是极富有意义的研究工作,我们曾报道钛的稳定水溶体系和应用这水溶钛体系合成茂钛金属有机化合物.本文首例报道茂锆的水溶体系与芳基羧酸钠盐水溶液的反应,得到一类新型的含有一个μ_3-O的三核茂锆羧酸离子型配合物,[Zr_3(μ_3-O)(μ_2-OH)_3(μ_2-ArCO_2)3(η-C_5H_5)_3]~+ArCO_2~-,测定了配合物(I)(Ar-O-ClC_6H_4)的晶体和分子结构。Cp_2ZrCl_2与乙酰丙酮在水中制备的水溶
The aqueous phase chemistry of titanium and zirconium metal organic compounds is a very significant research work, we have reported the stable titanium-based water-soluble system and the application of this water-soluble titanium system to synthesize metallocene compounds.In this paper, Aryl-carboxylic acid sodium salt aqueous solution to obtain a novel tri-nuclear zirconium carboxylate ionic complex containing a μ_3-O, [Zr_3 (μ_3-O) (μ_2-OH) _3 (μ_2-ArCO_2) 3 (η-C_5H_5) _3] ~ + ArCO_2 ~ - were used to determine the crystal and molecular structure of the complex (I) (Ar-O-ClC_6H_4). Water-soluble Cp_2ZrCl_2 prepared with acetylacetone in water