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The title complex (C26H18CuN2O6,Mr=517.96) has been synthesized by the reac-tion of α-furanacrylic acid with 1,10-phenanthroline (phen) in the solvent mixture of water and methanol. Crystal data: monoclinic,space group C2/c with a =2.2927(4),b=1.01248(18),c=1.05061(18) nm,β=111.188(3)o,V=2.274(7) nm3,Dc=1.513 g/cm3,Z=4,F(000)=1060,μ= 1.007mm?1,R=0.0320 and wR=0.0781. The crystal structural analysis shows that the copper atom is coordinated with four oxygen atoms from two α-furacrylic acids and two nitrogen atoms from 1,10-phenanthroline,giving a distorted octahedral coordination geometry. The result of electroche-mical analysis shows that the electron transfer in the electrode reaction is quasi-reversible.
The title complex (C26H18CuN2O6, Mr = 517.96) has been synthesized by the reac tion of a-furanacrylic acid with 1,10-phenanthroline (phen) in the solvent mixture of water and methanol. Crystal data: monoclinic, space group C2 / c = 1.05061 (18) nm, β = 111.188 (3) o, V = 2.274 (7) nm3, Dc = 1.513 g / cm3, and Z = 4 , F (000) = 1060, μ = 1.007 mm -1, R = 0.0320 and wR = 0.0781. The crystal structural analysis shows that the copper atom is coordinated with four oxygen atoms from two α-furacrylic acids and two nitrogen atoms from 1 , 10-phenanthroline, giving a distorted octahedral coordination geometry. The result of electrochem-mical analysis shows that the electron transfer in the electrode reaction is quasi-reversible.