应变和氯离子浓度对304不锈钢点蚀敏感性的影响(英文)

来源 :Chinese Journal of Chemical Engineering | 被引量 : 0次 | 上传用户:wanfl1985
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The effects of strain and chloride concentration on pitting susceptibility for type 304 stainless steel were studied in situ using the electrochemical technology under constant strain.The impact factor fεwas brought forward to value the effect of strain on pitting.The pitting behaviors of type 304 stainless steel in various chloride concen- trations under the strain levels 0%,10%,and 30%were investigated.Potentiostatic polarization technology was used to study how the chloride concentration affected corrosion current density.The results indicated that fεin- creased substantially and pitting potential varied remarkably when chloride concentration was over 90 mg·L -1 .Un- der the three levels of strain mentioned above,when chloride concentration was below 463 mg·L -1 ,121 mg·L -1 ,and 98 mg·L -1 ,respectively,the pitting potential shifted towards positivity and,the passive film became more stable. When the strain was below 10%,the pitting susceptibility of type 304 stainless steel varied greatly as strain in- creased,whereas the susceptibility only changed a little when the strain was over 10%. The effects of strain and chloride concentration on pitting susceptibility for type 304 stainless steel were studied in situ using the electrochemical technology under constant strain. The impact factor fεwas brought forward to value the effect of strain on pitting. Pitting behaviors of type 304 stainless steel. in various chloride concen- trations under the strain levels 0%, 10%, and 30% were investigated. Potentiostatic polarization technology was used to study how the chloride concentration affected corrosion current density. The results indicate that fεin- creased substantially and pitted potential varied varied remarkably when chloride concentration was over 90 mg · L -1 .Un-der the three levels of strain above, when chloride concentration was below 463 mg · L -1, 121 mg · L -1, and 98 mg · L -1 , respectively, the pitting potential shifted towards positivity and, the passive film became more stable. When the strain was below 10%, the pitting susceptibility of type 304 stainless steel varied greatly as strain in- creased, as the susceptibility only changed a little when the strain was over 10%.
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