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合成了以苯硒酚为配体的四核银簇阴离子化合物［Ｍｅ４Ｎ］２［Ａｇ４（ＳｅＰｈ）６］·ＣＨ３ＯＨ，并用Ｘ射线单晶衍射法测定了其晶体结构．簇阴离子的核心Ａｇ４Ｓｅ６是由４个Ａｇ原子组成的四面体内接于６个Ｓｅ原子组成的变形八面体中，形成了类金刚烷型结构
The tetranuclear silver cluster anion [Me4N] 2 [Ag4 (SePh) 6] · CH3OH with benzeneselenophenol as the ligand was synthesized and characterized by X-ray single crystal diffraction. The core of cluster anion Ag4Se6 is a tetrahedron composed of 4 Ag atoms, which is connected with the deformed octahedron composed of 6 Se atoms to form an adamantane type structure