一种定性评估同系列聚合物水动力学半径大小的方法

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水动力学半径是衡量聚合物注入能力的重要参数.通过统计同系列的普通聚合物(部分水解聚丙烯酰胺)和疏水缔合聚合物的产品质量检测结果,并测量相应聚合物的水动力学半径,分析聚合物Huggins常数与性能参数关系,得到一种定性评估同系列聚合物水动力学半径大小的方法.Huggins常数变化与聚合物分子结构、官能团有关,一定条件下,部分水解聚丙烯酰胺的Huggins常数随水解度增加呈指数增加趋势,疏水缔合聚合物的Huggins常数随黏度增加呈现线性增加趋势,少数分子结构异化的聚合物偏离上述变化规律.因此根据产品质量检测结果,统计2种聚合物的Huggins常数与性能参数关系,可以较简易准确地对比评价同系列聚合物的水动力学半径相对大小.
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