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以双二茂铁丙烷基乙炔和顺-1,2-二氯乙烯为原料,合成了新的双二茂铁丙烷基乙炔基化合物1-氯-4-双二茂铁丙烷基-1-丁烯-3-炔[FcC(CH3)2Fc’C≡C—CH=CHCl(Fc=C5H5FeC5H4,Fc’=C5H5FeC5H3)]。利用红外光谱、核磁共振谱、质谱和元素分析等分析测试手段,对化合物的组成和结构进行了分析,确定了标题化合物的分子结构。
A novel bis (ferrocene) propylethynyl compound, 1-chloro-4-bisferrocenylpropane-1-butene, was synthesized from bisferrocenylpropyl acetylene and cis-1,2-dichloroethylene -3-yne [FcC (CH3) 2Fc’C≡C-CH = CHCl (Fc = C5H5FeC5H4, Fc ’= C5H5FeC5H3)]. The structure and composition of the compounds were analyzed by IR, NMR, MS and elemental analysis to determine the molecular structure of the title compound.