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近年来,电子计算机在分析化学中的应用已为人们所重视。无掩蔽剂存在下金属离子与有机试剂反应最佳酸度(pH)_(opt)的计算方法曾有报道,并用于研究反应的机理等理论性的问题。本文借助电子计算机探讨了具掩蔽剂存在的情况下,金属离子与有机试剂反应条件的合理选择这一问题,编写出“SATE-YIANBIJI”BASIC程序,可以快速获取一系列信息,预测反应条件,对实际工作有指导作用。同时,也能用于预测反应产物及反应机理。
In recent years, the application of electronic computers in analytical chemistry has been valued by people. The calculation of the optimum acidity (pH) _ (opt) for the reaction of metal ions with organic reagents in the absence of masking agent has been reported and used to study the theoretical issues such as the mechanism of reaction. In this paper, we discuss the reasonable choice of the reaction conditions between metal ions and organic reagents in the presence of masking agents, and write “SATE-YIANBIJI” BASIC program, which can quickly obtain a series of information and predict the reaction conditions. Practical work has a guiding role. At the same time, it can also be used to predict reaction products and reaction mechanism.