综述了近十年来铟试剂在有机合成中的应用。重点讨论了铟试剂参与的有关碳-碳键形成的反应,如羰基化合物的烯丙基化、Reformatsky反应、成环以及三氯化铟作为Lewis酸的催化反应以及铟试剂的水相反应化学。铟试剂的这些反应,尤其是水相反应具有其它金属有机试剂在化学选择性和立体选择性方面具有独特的优势。 The applications of indium reagents in organic synthesis in recent ten years are summarized. The reactions involved in the formation of carbon-carbon bonds by indium reagents, such as the allylation of carbonyl compounds, Reformatsky reaction, ring formation, and the reaction of indium trichloride as a Lewis acid and the aqueous reaction chemistry of indium reagents, are mainly discussed. These reactions of indium reagents, especially aqueous reactions, have unique advantages over other metal-organic reagents in terms of chemical selectivity and stereoselectivity.