【摘 要】
:
The title platinaborane, [(P (2) Ph 3)Pt (1) ( μ 2 B (11) (B (9) OC~(CH 3) 3 B 10 ~H 10 ))Pt (7) (P (1) Ph 3)] 2
【出 处】
:
Chinese Journal of Chemistry
论文部分内容阅读
The title platinaborane, [(P (2) Ph 3)Pt (1) ( μ 2 B (11) (B (9) OC~(CH 3) 3 B 10 ~H 10 ))Pt (7) (P (1) Ph 3)] 2, a triple cluster, which is a binuclear Pt complex dimmer, was prepared. Single crystal X ray diffraction analysis shows that a Pt (7) atom served as a common vertex between cluster {PtB 10 } and {Pt 4}. The {Pt 4} cluster is of parallelogram.
The title platinaborane [(P (2) Ph 3) Pt (1) (μ 2 B (11) (B (9) OC ~ (CH 3) 3 B 10 ~ H 10) 1) Ph 3)] 2, a triple cluster, which is a binuclear Pt complex dimmer, was prepared. Single crystal X ray diffraction analysis shows that a Pt (7) atom served as a common vertex between cluster {PtB 10} and { Pt 4}. The {Pt 4} cluster is of parallelogram.
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