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薄层电解池电化学技术,即用机械的方法造成电极表面附近具有200μm以下厚度的均匀溶液层的特殊方怯。这种技术由于限制了溶液的扩散效应,可以在较短时间内完全电解薄层中的反应物而不同于通常的电化学方法。采用这种电化学技术时,对于电极反应的数学处理,勿需考虑扩散的影响,所以就比较简单。这种方法最初是由 F.C.Anson从一支偶然破裂的铂电极引起的异常现象中发现的。之后,他细心地研究了这种异常现象,提出了薄层电化学技术这种新的方法。
Thin-layer cell electrochemical techniques, ie, the use of mechanical methods to cause special problems in uniform solution layers near the electrode surface with thicknesses below 200 μm. This technique, due to the limitation of the diffusion effect of the solution, can completely electrolyze the reactants in the thin layer in a shorter time than the usual electrochemical methods. The use of this electrochemical technique, the mathematical treatment of the electrode reaction, do not need to consider the impact of proliferation, so it is relatively simple. This method was first discovered by F.C.nson from the anomalies caused by a ruptured platinum electrode. Later, he carefully studied this anomaly and proposed a new method of thin-layer electrochemical technique.