EFFECTS OF Pb COMPOUND ADDITIVES ON THE PROPERTIES OF YBa_2Cu_3O_(7-δ)

来源 :Acta Metallurgica Sinica(English Letters) | 被引量 : 0次 | 上传用户:gx8689326
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The melting temperature and critical transition temperature Tc of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When PbO was doped in YBa2Cu3O7-δ, the melting temperature of YBa2Cu3O7-δ was reduced, however its superconductivity was weakened. From the XRD pattern of the sintered mixture of YBa2Cu3O7-δ and PbO, it was known that there was a reaction between YBa2Cu3O7-δ and PbO, and the product was BaPbO3. Hence different contents of BaPbO3 (10mass%, 20mass% and 30mass%) were added in YBa2Cu3O7-δ. It was proved that there were no reactions between YBa2Cu3O7-δ and BaPbO3. And the superconductivity of the mixtures was much better than that of the samples with PbO additive. The melting temperature and critical transition temperature Tc of YBa2Cu3O7-δ with deferent content additives of PbO and BaPbO3 were studied. When the PbO was doped in YBa2Cu3O7-δ, the melting temperature of YBa2Cu3O7-δ was reduced, however, its its superconductivity was weakened. XRD pattern of the sintered mixture of YBa2Cu3O7-δ and PbO, it was known that there was a reaction between YBa2Cu3O7-δ and PbO, and the product was BaPbO3. Added in YBa2Cu3O7-δ. It was verified that there were no reactions between YBa2Cu3O7-δ and BaPbO3. And the superconductivity of the mixtures was much better than that of the samples with PbO additive.
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