Synthesis and Spectroscopic Properties of a Series of New tetra-Substituted Metal Phthalocyanines

来源 :Chemical Research in Chinese Universities | 被引量 : 0次 | 上传用户:a369747001
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A new class of metal phthalocyanines(MPcs) containing four 8-quinolinol(8-QH) derivative moieties were successfully synthesized and characterized by mass spectroscopy, IR, UV-Vis and element analysis, the results of which were consistent with the proposed structures. All of them can dissolve in common organic solvents, such as dichloromethane, chloroform, and acetone. The effect of metal ion on the absorption of Q band was studied with UV-Vis spectra. The fluorescent properties for those complexes were also investigated. A new class of metal phthalocyanines (MPcs) containing four 8-quinolinol (8-QH) derivative moieties were successfully synthesized and characterized by mass spectroscopy, IR, UV-Vis and element analysis, the results of which were consistent with the proposed structures. The effect of metal ion on the absorption of Q band was studied with UV-Vis spectra. The fluorescent properties for those complexes were also investigated.
其他文献
陶瓷钢管是采用自蔓延离心法技术生产的,其组织结构独特,有高的硬度和强度,有良好的抗机械冲击和热冲击的综合性能,耐磨性高于铸石管、耐磨铸钢管等,工程造价低,能直接切割、
10月11日,来自全国的46家实达电脑分货商代表齐聚福州,参加了在此间举行的首届实达电脑分货商大会。本次分货商大会围绕“研讨、促进、规范、发展”的主题,就实达电脑的渠道
[目的]评价伽玛刀(γ刀)联合热化疗治疗原发性肝癌的治疗效果。[方法]2004年7月至2006年7月,原发性肝癌病人53例给予γ刀联合热疗治疗,其中20例同时联合化疗。[结果]全部患者
Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investig
兰州市副市长杨在溪、市委秘书长殷吉平下台,前任兰州市长张玉舜被捕,兰州市委书记王军遭免职。短短几个月,兰州政府高层强烈地震。这一切从张国芳被有关部门实施强制措施开
9月11日,自治区党委公布了《关于广西实施科学发展三年计划的决定》。《决定》要求,要坚定不移地走新型工业化和城镇化道路,着力构建具有广西特色的现代产业新体系。要优先发
SAP执行董事会成员Peter Zencke博士10月26日在北京发表了“网络经济中创造用户”价值的演说,他向我们提出在网 Dr. Peter Zencke, a member of the SAP Executive Board,
目的:观察应用WhiteStar行白内障超声乳化吸除术的临床疗效.方法:老年性白内障各30例30眼分别应用配有WhiteStar的超声乳化机和不配有WhiteStar超声乳化机行白内障超声乳化吸除人工晶体植入术,比较两组结果.两组术前指标无统计学差异.观察术后一天、一周视力,术后切口及角膜情况,并于术后三天查角膜内皮情况.结果:两组术后一天视力WhiteStar组为0.67±0.18(术前为0.1
6月30日获悉:如何保证ThinkPad笔记本电脑上保存的有关业务的、至关重要的数据能规避丢失、被盗或损坏的风险?IBM的PC数据保险库(PC Data Vaulting),就是为备份和恢复ThinkP
第4届中美(Sino-US)教授会于2008年6月12—13日在北京大学医学部成功举行。此次会议由北京大学天然药物及仿生药物国家重点实验室承办,是一次旅美华人有机化学教授与国内同行