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An unusual two-dimensional supramolecular complex, namely, [Cd_2(Cl)_4(L)_2](1), has been synthesized by 2-(1 H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol(L) and CdCl_2·2.5H_2O under hydrothermal conditions. The compound was characterized by eleme