合成了二(草酸根或环庚三烯酚酮基)·苯基乙二胺合钴(Ⅲ)配合物,采用离子交换法提纯和分离了该配合物的非对映异构体对,并通过光谱法归属了异构体的空间构型,对其紫外可见光谱等性质也进行了研究。 The bis (oxalate or cycloheptatrone phenolic ketone) · phenylethylenediamine cobalt (Ⅲ) complex was synthesized and the diastereoisomeric pairs of the complex were purified and separated by ion exchange method The spatial configuration of the isomers was assigned by spectroscopy, and their UV-vis spectra were also studied.