制备了异烟酸氮氧化物(简计为HINO)/磷钼酸镍有机-无机络合物({[Ni(H2O)8][H(H2O)2.5](HINO)4(PMo12O40)}n;简计为1)掺杂硅胶复合物(简计为1-SG1);采用红外光谱仪和X射线衍射仪证实了合成产物的结构.结果表明,化合物1的结构特征在1-SG1硅胶复合物中得以保留.与此同时,在约98%的相对湿度下,1-SG1在温度55~100℃范围内显示良好的导电性,其质子导电率达到8.98×10-3~1.03×10-2 S·cm-1;并且,在同等条件下,1-SG1的质子导电性优于化合物1. An isonicotinic acid oxynitride (abbreviated as HINO) / nickel phosphomolybdate organic-inorganic complex ({[Ni (H2O) 8] [H (H2O) 2.5] (HINO) 4 (PMo12O40)} n (Abbreviated as 1-SG1), and the structure of the synthesized product was confirmed by infrared spectroscopy and X-ray diffractometry.The results showed that the structural characteristics of compound 1 were similar to those of 1-SG1 silica gel composite In the meantime, at about 98% relative humidity, 1-SG1 showed good conductivity at a temperature of 55 to 100 ° C, and its proton conductivity reached 8.98 × 10 -3 to 1.03 × 10 -2 Cm-1; and, under the same conditions, the proton conductivity of 1-SG1 is superior to that of compound 1.