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合成了第一过渡金属铬~锌7种氯化物与L-α-组氨酸的固态配合物,确定了它们的组成.用精密转动弹热量计测定了它们的恒容燃烧能,计算了它们的标准摩尔燃烧焓和标准摩尔生成焓.其标准摩尔生成焓与金属的原子序数作图,呈现出锯齿形规律.
Their solid-state complexes were synthesized and their compositions were determined. Their permanent-charge combustion energies were measured by a precision rotary calorimeter, and they were calculated The standard molar enthalpy of combustion and the standard molar enthalpy of formation.The standard molar enthalpy of formation is plotted against the atomic number of the metal and shows a sawtooth pattern.