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In this work,a CoNxC active sites-rich three-dimensional porous carbon nanofibers network derived from bacterial cellulose and bimetal-ZIFs is prepared via a nucleation growth strategy and a pyrolysis process.The material displays excellent electrocatalytic activity for the oxygen reduction reaction,reaching a high limiting diffusion current density of-7.8 mA cm-2,outperforming metal-organic frameworks derived multifunctional electrocatalysts,and oxygen evolution reaction and hydrogen evolution reaction with low overpotentials of 380 and 107 mV,respectively.When the electrochemical properties are further evaluated,the electrocatalyst as an air cathode for Zn-air batteries exhibits a high cycling stability for 63 h as well as a maximum power density of 308 mW cm-2,which is better than those for most Zn-air batteries reported to date.In addition,a power density of 152 mW cm-2 is provided by the solid-state Zn-air batteries,and the cycling stability is outstanding for 24 h.The remarkable electrocat-alytic properties are attributed to the synergistic effect of the 3D porous carbon nanofibers network and abundant inserted CoNxC active sites,which enable the fast transmission of ions and mass and simultaneously provide a large contact area for the electrode/electrolyte.