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利用催化氢化合成醚的新方法BethmontV等[TetrahedronLett,1995;36:4235]醛或酮与一级或二级醇用10%Pd/C作催化剂,在40bar的氢压、50或100℃下氢化,可合成对称或非对称的一级或二级醚类。7例中有5例收率≥9...
A New Method for the Synthesis of Ethers by Catalytic Hydrogenation Bethmont V et al [Tetrahedron Lett, 1995; 36: 4235] aldehydes or ketones with primary or secondary alcohols using 10% Pd / C as catalyst under hydrogen pressure of 40 bar at 50 or 100 ° C , Symmetrical or asymmetric primary or secondary ethers can be synthesized. Five of seven patients had a yield of ≥9 ...