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The polymeric solid, [Cu(bpy)(tp)(H2O)]n 1 (tp = terephthalate, bpy = 2,2’-bipyri- dine), has been obtained from the hydrothermal approach and characterized by X-ray diffraction, elemental analysis, IR spectra and thermogravimetric analysis. Compound 1 crystallizes in triclinic, space group P1 with a = 9.360(2), b = 9.872(2), c = 10.774(2) , α = 106.281(5), β = 112.471(5), γ = 96.697(3)o, V = 854.5(3) 3, Z = 2, GOF = 1.09, R = 0.0318 and wR = 0.0845. X-ray single-crystal analysis reveals that 1 is an interesting 3D staggered brickwall-like supramolecular array assembled through aromatic π-π stacking and hydrogen bonding interactions of 1D infinite zigzag polymeric chains.
The polymeric solid, [Cu (bpy) (tp) (H2O)] n 1 (tp = terephthalate, bpy = 2,2’-bipyri- dine) has been obtained from the hydrothermal approach and characterized by X-ray diffraction Compound 1 crystallizes in triclinic space group P1 with a = 9.360 (2), b = 9.872 (2), c = 10.774 (2) 112.471 (5), γ = 96.697 (3) o, V = 854.5 (3) 3, Z = 2, GOF = 1.09, R = 0.0318 and wR = 0.0845. interesting 3D staggered brickwall-like supramolecular array assembled through aromatic π-π stacking and hydrogen bonding interactions of 1D infinite zigzag polymeric chains.