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统计有关键长,发现Tc氧化态对Tc-L键长的影响不如其他因素显著。例举了一些还原剂大大过量,但Tc却能稳定于某一价态的事实,以及十几种已测定结构的平均氧化态为非整数的Tc化合物,认为配位环境是决定Tc氧化态的首要因素。
Statistical key length, found Tc oxidation state Tc-L bond length is not as significant as other factors. Some examples are given of the fact that Tc can be stabilized in a certain valence state by a large excess of reductant and Tc compounds in which the average oxidation state of a dozen of structures have been determined to be non-integer. The coordination environment is thought to determine the oxidation state of Tc Prime factor.