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环糊精(准)聚轮烷是由环糊精与链状高分子通过非共价键结合得到的超分子结构。由于它具有自组装特性、生物相容性、分子识别能力而受到广泛关注。综述了影响环糊精(准)聚轮烷自组装的各种因素,并从反应热力学的角度进行推测和解释。
Cyclodextrin (quasi) polyrotaxane is a supramolecular structure obtained by combining cyclodextrin and a chain polymer through non-covalent bonding. Due to its self-assembly properties, biocompatibility, molecular recognition and receive widespread attention. The various factors affecting the self-assembly of cyclodextrin (quasi) polyrotaxane are reviewed and the conjectures and explanations are given from the perspective of reaction thermodynamics.