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总结了作者近几年在硼磷酸盐研究中所合成和表征的 10多个新化合物 ,即元素周期表第 4周期从 Cr至 Ga的元素或氧化物与工业催化剂材料 BPO4 在高温固相反应中 ,分别合成出具有 3种结构类型的新化合物 :新结构类型的三方 Cr2 [BP3 O12 ]、正交 Al PO4 型的 (B,M) [PO4 ](M=Mn,Fe,Co,Ni,Cu,Zn)和新型四方 (Ga,B) PO4 ;用水热法合成出 Na Ga[BP2 O7(OH) 3 ]、Na2 In2 [PO3 (OH) ]4· H2 O和 Na4 Co3 H2 (PO4 ) 4· 8H2 O等新化合物 .同时还讨论了硼磷酸盐化合物研究的最新进展及结构化学的一般规律 .
The authors summarized more than 10 new compounds synthesized and characterized in recent years by the author in the study of boron phosphate, that is, the fourth cycle of the periodic table of elements from Cr to Ga or oxide and the industrial catalyst BPO4 in high temperature solid state reaction , New compounds with three structural types were synthesized respectively: the new structural type tripartite Cr2 [BP3 O12], orthorhombic Al PO4 (B, M) [PO4] (M = Mn, Fe, Co, Ni, Cu , Na 2 [PO 3 (OH)] 4 · H 2 O and Na 4 Co 3 H 2 (PO 4) 4 · 8H2O and other new compounds.At the same time, the latest progress of the research on boron phosphate compounds and the general rules of structural chemistry are also discussed.