【摘 要】
：
Lithium metal is a promising anode material owing to its very low electrochemical potential and ultrahigh specific capacity.However,the growth of lithium dendrites could result in a short lifespan,low coulombic efficiency,and potential safety hazards duri
【机 构】
：
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University
论文部分内容阅读
Lithium metal is a promising anode material owing to its very low electrochemical potential and ultrahigh specific capacity.However,the growth of lithium dendrites could result in a short lifespan,low coulombic efficiency,and potential safety hazards during the progress of lithium plating/stripping.These factors drastically hinder its application in lithium metal batteries.This review focuses on the use of three dimensional (3D) porous host frameworks to improve Li plating/stripping behaviors,accommodate the change in volume,and suppress or block lithium dendrite growth.Various 3D porous frameworks,including the conductive carbon-based,metal-based,and lithiophilic inorganic-compound frameworks are introduced and summarized in detail.The particular functions,relative developments,and optimized strategies of various 3D porous frameworks for lithium deposition/dissolution behaviors are discussed.Moreover,the challenges and promising developments in the field of Li metal anodes will be discussed at the end of this review.
其他文献
It is an urgent task to develop highly efficient non-noble metal electrocatalysts in the direction of ORR,but still a huge and long-term challenge.Herein,an efficient one-step pyrolysis of Sichuan pepper powder,2,2-bipyridine,FeCl3,NaSCN,and ZnCl2 at 900
The low-temperature physical vapor deposition process of atomically thin two-dimensional transition metal dichalcogenide (2D TMD) has been gaining attention owing to the cost-effective production of diverse electrochemical catalysts for hydrogen evolution
The device preconditioning dependent hysteresis and the consequential performance degradation hinder the actual performance and stability of the perovskite solar cells.Ion migration and charge trapping in the perovskite with large contribution from grain
To study the effect of adjacent hydroxyl to the active sites,several acid catalysts,i.e.substituted benzoic acids with adjacent carboxyl are employed in the fructose dehydration to 5-hydroxymethylfurfural (HMF).Experimental results reveal that Brφnsted ac
In the light of wireless and non-fossil society based on portable electronics, electric vehicles, and smart grids, secondary batteries with higher energy density, faster charge, and safer operation are pursued persistently [1].Nowadays, commercial lithium
Structural and compositional design of core-shell structure is an effective strategy towards enhanced catalysis.Herein,amorphous MnO2 nanosheets and K+-intercalated layered MnO2 nanosheets are controllably assembled over Fe2O3 spindles,in which the MnO2 n
A series of Pt/C catalysts for proton exchange membrane fuel cells (PEMFCs) with various metal Ioadings is synthesized by a microwave-assisted polyol process via mixing an extremely stable platinum colloid (＞ 3 months\' shelf life) from single batch pre
Carbon materials have been widely used as electrodes,but the mechanistic roles are still not clear due to the complexity of the carbon surface chemistry.Herein we clarify that intrinsic material properties of carbon have to be activated by extrinsic facto
Metal-organic framework (MOF) derived hybrid materials have been developed as an efficient non-noblemetal electrocatalysts for clean energy conversion systems.In this work,a Co-based MOF containing nitrogen and oxygen heteroatoms (Co-NOMOF) mixed with the
Ordered hierarchical architectures are attractive candidates for electrochemical energy storage applications.Herein,a facile self-template strategy is applied to prepare Fe7Se8 architectures with a monolithic structure via a self-synthesized single precur