本文以甲苯或甲苯—汽油的混合物为致孔剂,合成了一系列丙烯醛-二乙烯苯大孔共聚体,通过对共聚体孔结构参数的测定,讨论了影响共聚体孔结构的主要因素。丙烯醛-二乙烯苯大孔共聚体与某些氨的衍生物作用,制得了若干新型螯合树脂,它们对Au~(3+)表现出不同的亲合力,其中腙型树脂对AuCI_4~-的静态吸附量可达964mgAu(Ⅲ)/g干树脂 In this paper, a series of acrolein-divinylbenzene macroporous copolymers were synthesized by using toluene or toluene-gasoline mixtures as pore-forming agents. The main factors affecting the pore structure of the copolymers were discussed by measuring the pore structure parameters of the copolymers. Acrolein - divinylbenzene macroporous copolymer with some ammonia derivatives, a number of new chelating resins were obtained, which showed different affinity to Au ~ (3+). Among them, hydrazone - The static adsorption capacity of up to 964mgAu (Ⅲ) / g dry resin