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The mononuclear manganese complex Mn(phen)(CF3COO)(H2O)3NO3 (C14H14- O8N3F3Mn) has been synthesized, where phen = 1,10-phenanthroline. The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/c with a = 8.8550(3), b = 10.6529(3), c = 19.8763(2) ? ?= 97.762(2), V = 1857.78(8) 3, Z = 4, Mr = 464.22, Dc = 1.660 g/cm3, ?= 0.789 mm-1, F(000) = 940, T = 293(2) K, R = 0.0764 and wR = 0.2441 for 1995 observed reflections with I > 2s(I). In the crystal the manganese atom is six-coordinated by two chelated nitrogen atoms from phenanthroline, three oxygen atoms from water molecules and one oxygen atom from trifluoroacetate, completing an octahedral geometry.
The mononuclear manganese complex Mn (phen) (CF3COO) (H2O) 3NO3 (C14H14- O8N3F3Mn) has been synthesized, where phen = 1,10-phenanthroline. The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic space group P21 / c with a = 8.8550 (3), b = 10.6529 (3), c = 19.8763 (2) = 97.762 (2), V = 1857.78 , Mr = 464.22, Dc = 1.660 g / cm3,? = 0.789 mm-1, F (000) = 940, T = 293 (2) K, R = 0.0764 and wR = 0.2441 for 1995 observed reflections with I> I). In the crystal the manganese atom is six-coordinated by two chelated nitrogen atoms from phenanthroline, three oxygen atoms from water molecules and one oxygen atom from trifluoroacetate, completing an octahedral geometry.