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本文在测定五个新颖的双核钼（Ｖ）簇合物的晶体结构 和 以及文献报导数据的基础上，综 述了含氧桥双核钼（Ｖ）簇合物的结构特征，并应用ＣＬＤ－ＭＯ方法探讨了该类化合物的电子结 构。
In this paper, the crystal structure of five new binuclear molybdenum (V) clusters and their reported data were reviewed, and the structural characteristics of the binuclear molybdenum (V) cluster containing oxygen bridge were reviewed. The CLD-MO method The electronic structures of these compounds were discussed.