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合成了4种新型的四苯并卟啉衍生物(简记为T_(-PyPA)PP,T_(-αMPyPA)PP,T_(-γMPyPA)PP,T_(-,γDMPyPA)PP),对其进行了表征,并在乙酸缓冲溶液中研究了它们与Cu~(2+)离子的反应动力学,提出了该类卟啉与Cu~(2+)反应的可能反应机理。
Four new tetraphenylporphyrin derivatives (abbreviated as T_ (- PyPA) PP, T_ (- αMPyPA) PP, T_ (- γMPyPA) PP, T_ (-, γDMPyPA) PP) The kinetics of their reaction with Cu 2+ ions was studied in acetic acid buffer solution and the possible reaction mechanism of this porphyrin reaction with Cu 2+ was proposed.